It won't be a problem if you use AVCWare
iPod to iPod/Computer/iTunes Transfer, even though you don't have iTunes library.
It helps you to add audio and video files from your PC to your iPod/iPhone, such as music and movies. On the other hand, it can also transfer files from iPod to computer.
Wish this can help and good luck.
I think its step by step guide is most helpful.
http://iphone-to-computer.net/transfer-songs-videos-photos-playlists-from-ipod-to-computer-itunes.html
It is easy to use and you can try it now.
http://www.google.com/search?hl=en&newwindow=1&q=site%3Aiphone-to-computer.net++avcware+ipod+transfer&btnG=Search&aq=f&oq=&aqi=